This poster investigates the influence of lithium-ion battery (LIB) cell form factors, including cylindrical, prismatic, and pouch configurations, together with electrode architectures such as jelly-roll, stacked, and blade designs, on electrochemical performance, thermal safety, manufacturability, and pack-level integration across major commercial chemistries, including LiFePO4 (LFP), Li(NiMnCo)O2 (NMC), LiNiCoAlO2 (NCA), and LiCoO2 (LCO). Literature studies, OEM datasheets, and teardown analyses published between 2015 and 2025 were evaluated to establish the relationships between cell geometry, electrode configuration, and battery behavior under practical operating conditions. The comparative analysis highlights significant trade-offs among gravimetric and volumetric energy density, thermal runaway resistance, cycle life, power capability, and manufacturing scalability. LFP chemistry demonstrates superior thermal stability, safety, and long-term cycling durability, making it particularly suitable for prismatic and blade-type architectures used in electric vehicles and stationary energy-storage systems, despite its relatively low operating voltage and moderate energy density. In contrast, NMC and NCA chemistries offer higher specific energy and power densities, especially when integrated with a jelly-roll architecture and advanced tabless or multi-tab current-collection strategies that improve current homogeneity and manufacturing efficiency. Pouch cells offer excellent energy-to-weight ratios and the advantages of flexible packaging, but require precise mechanical compression and thermal management to ensure structural stability and electrochemical reliability. Although LCO remains largely restricted to portable electronics due to safety and cost constraints, emerging LiMnFePO4 (LMFP) cathodes offer promising opportunities to enhance voltage and energy density while maintaining the cost effectiveness and cycling stability associated with phosphate-based systems. Overall, this poster establishes an application oriented framework linking cell chemistry, form factors, and electrode architecture to support the design and optimization of next-generation LIB technologies.