To improve the stability and catalytic efficiency of electrocatalyst materials used for alcohol electrooxidation in basic environments, various carbon supports (CSs) are utilized, onto which one or more active metals are anchored to introduce electrochemically stable active sites. In this work, the electrooxidation of four key C1-C3 alcohols (methanol, ethanol, ethylene glycol, and glycerol) is demonstrated using a Pd-decorated carbon nanofiber (Pd/CNF) electrocatalyst prepared via a facile chemical reduction of commercial carbon nanofibers. The morphology and chemical composition of the Pd/CNF electrocatalyst are investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). Electrochemical analysis confirms that the prepared Pd/CNFs, featuring an electrochemically active surface area (ECSA) of 28.76 m² g⁻¹, exhibit a significantly enhanced ECSA compared to Pd/C (13.52 m² g⁻¹), along with greater catalytic efficiency during ethylene glycol electrooxidation (EGOR). The outstanding electrocatalytic behavior of the Pd/CNFs is attributed to their unique structure and the synergistic interaction between palladium nanoparticles and the carbon nanofiber support. Owing to their superior conductivity, strong catalytic activity, and stability, the synthesized Pd/CNFs show great potential as electrocatalysts for alkaline fuel cells.